Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex.
نویسندگان
چکیده
A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods--including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies--were used to characterize this new uranyl complex.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 19 شماره
صفحات -
تاریخ انتشار 2013